Organocapture: Difference between revisions
(Created page with " '''Organocapture''' When small organic molecules, rather than transition metal complexes, enzymes or mere acids/bases, catalyze a reaction, the term "organocatalysis" is used. Sometimes the "catalyst" increases the yield of a reaction without accelerating the reaction leading to the desired product by reducing the rate of competing reactions more than that of the desired reaction. When this happens and a covalent intermediate is involved, the term "organocapture" may...") |
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== Organocapture == | |||
When small organic molecules, rather than transition metal complexes, enzymes or mere acids/bases, catalyze a reaction, the term "organocatalysis" is used. Sometimes the "catalyst" increases the yield of a reaction without accelerating the reaction leading to the desired product by reducing the rate of competing reactions more than that of the desired reaction. When this happens and a covalent intermediate is involved, the term "organocapture" may be used. | When small organic molecules, rather than transition metal complexes, enzymes or mere acids/bases, catalyze a reaction, the term "organocatalysis" is used. Sometimes the "catalyst" increases the yield of a reaction without accelerating the reaction leading to the desired product by reducing the rate of competing reactions more than that of the desired reaction. When this happens and a covalent intermediate is involved, the term "organocapture" may be used. | ||
== References == | |||
=== Organocatalysis === | |||
[1] B. List, R. A. Lerner, C. F. Barbas III. Proline-catalyzed direct asymmetric aldol reactions. ''J. Am. Chem. Soc.'' '''2000''', ''122'', 2395–2396. https://doi.org/10.1021/ja994280y | |||
B. List, R. A. Lerner, C. F.Barbas III. Proline-catalyzed direct asymmetric aldol reactions. ''J. Am. Chem. Soc.'' '''2000''', ''122'', 2395–2396. | |||
''' | [2] D. W. C. MacMillan, The advent and development of organocatalysis. ''Nature'' '''2008''', ''455'', 304–308. https://doi.org/10.1038/nature07367 | ||
=== Reference Organocapture === | |||
P. Tremmel, H. Griesser, U. E. Steiner, C. Richert, How small heterocycles make a reaction network of amino acids and nucleotides efficient in water. ''Angew. Chem. Int. Ed.'' '''2019''', ''58'', 13087-13092. | [3] P. Tremmel, H. Griesser, U. E. Steiner, C. Richert, How small heterocycles make a reaction network of amino acids and nucleotides efficient in water. ''Angew. Chem. Int. Ed.'' '''2019''', ''58'', 13087-13092. https://doi.org/10.1002/anie.201905427 | ||
Latest revision as of 11:36, 5 August 2024
Organocapture
When small organic molecules, rather than transition metal complexes, enzymes or mere acids/bases, catalyze a reaction, the term "organocatalysis" is used. Sometimes the "catalyst" increases the yield of a reaction without accelerating the reaction leading to the desired product by reducing the rate of competing reactions more than that of the desired reaction. When this happens and a covalent intermediate is involved, the term "organocapture" may be used.
References
Organocatalysis
[1] B. List, R. A. Lerner, C. F. Barbas III. Proline-catalyzed direct asymmetric aldol reactions. J. Am. Chem. Soc. 2000, 122, 2395–2396. https://doi.org/10.1021/ja994280y
[2] D. W. C. MacMillan, The advent and development of organocatalysis. Nature 2008, 455, 304–308. https://doi.org/10.1038/nature07367
Reference Organocapture
[3] P. Tremmel, H. Griesser, U. E. Steiner, C. Richert, How small heterocycles make a reaction network of amino acids and nucleotides efficient in water. Angew. Chem. Int. Ed. 2019, 58, 13087-13092. https://doi.org/10.1002/anie.201905427